Combine the water and kosher salt in a bowl. Stir until the salt dissolves completely. Submerge the pork chops in the brine and refrigerate for 1 hour.
4 cups water, ¼ cup kosher salt, 2 lbs bone-in pork chops
Remove the pork chops from the brine and pat them completely dry with paper towels.
2 lbs bone-in pork chops
Combine the ground black pepper, Italian seasoning, garlic powder, paprika, and brown sugar in a small bowl. Drizzle olive oil over the pork chops and rub to coat. Sprinkle the seasoning mixture evenly over both sides and gently press it into the meat.
½ teaspoon ground black pepper, 2 teaspoons Italian seasoning, 1 teaspoon garlic powder, ½ teaspoon paprika, 1 teaspoon brown sugar, 2 tablespoons olive oil, 2 lbs bone-in pork chops
Let the seasoned pork chops sit at room temperature for 30 minutes.
2 lbs bone-in pork chops
Preheat the oven to 375°F.
Heat a cast iron skillet over medium-high heat until very hot. Place the pork chops in the skillet and sear without moving for 2 to 3 minutes until a golden-brown crust forms. Flip and sear the other side for 2 minutes.
2 lbs bone-in pork chops
Reduce the heat to medium. Add the butter, smashed garlic, and rosemary to the skillet. Once the butter melts, tilt the pan slightly and use a spoon to baste the pork chops with the melted butter for about 1 minute.
2 tablespoons unsalted butter, 3 cloves garlic, 2 sprigs fresh rosemary
Transfer the skillet to the oven and bake for 8 minutes or until the internal temperature reaches 140°F.
Remove from the oven and transfer the pork chops to a serving plate. Let rest for 5 minutes. Spoon the pan juices over the pork chops before serving.